Start With the Core: Understanding Lithium Battery Fundamentals

Before diving into performance metrics, compliance, or pack design, it’s essential to master the core concepts of lithium batteries—from chemistry to cell structure.

Whether you’re sourcing batteries for e-bikes, solar systems, or medical devices, understanding the basics helps you avoid common selection errors, communicate with engineers, and make informed decisions.

This page walks you through the core knowledge every professional buyer, engineer, or project manager should know, including battery types, cell structure, material composition, key terms, and typical misunderstandings. No deep BMS theory or testing protocols here—just the essential groundwork.

Frequently Asked Questions – Lithium Battery Basics

What exactly is a lithium battery?

A lithium battery is a rechargeable energy storage device that uses lithium ions to move between the anode and cathode during charge and discharge cycles. It’s known for high energy density, low self-discharge, and long cycle life.

The three main types are cylindrical cells, prismatic cells, and pouch cells. Each type differs in structure, energy density, and suitability for specific applications like e-bikes, power tools, or storage systems.

Core materials include a positive electrode (cathode), negative electrode (anode), separator, electrolyte, and current collectors. These parts work together to enable the flow of lithium ions during operation.

Lithium ions move from the anode to the cathode during discharge and reverse during charging. This electrochemical process allows the battery to store and release energy efficiently.

What's the difference between Li-ion and LiFePO₄ batteries?

Li-ion batteries have higher energy density but lower thermal stability. LiFePO₄ offers longer cycle life and greater safety, making it ideal for applications requiring high reliability.

Cylindrical cells offer excellent mechanical stability, efficient heat dissipation, and mature production processes. They’re commonly used in power tools, e-bikes, and energy storage packs.

Yes—when properly designed with quality materials and BMS protection. Certifications like UN38.3, CE, and UL also help ensure compliance and safety for transport and use.

Absolutely. Battery packs can be tailored with different cell formats, capacities, and configurations depending on your voltage, current, and space requirements.

Table of Contents

Chapter 1

What Is a Lithium Battery?

A lithium battery is a device that stores electrical energy using lithium metal or lithium compounds. Understanding what a lithium battery cell is made of helps buyers assess whether a specific chemistry matches their application’s needs.

 

Broadly speaking, lithium batteries come in two categories:

  • Primary lithium batteries – Non-rechargeable, used in low-power devices.

  • Secondary lithium batteries – Rechargeable, including Li-ion and LiFePO₄ types. The difference between Li-ion and LiFePO4 lies in energy density, safety, and cycle life, making them suitable for different markets like EVs or solar storage.

Chapter 2

History and Development of Lithium Batteries

ithium battery technology began in the 1970s. Sony introduced the first commercial lithium-ion battery in 1991. Today, lithium batteries are widely used in electric vehicles, energy storage, and consumer electronics.

Key Milestones:

  • 1970s: First lithium metal batteries

  • 1991: Sony launches Li-ion

  • 2005–2020: Rise of EV and portable tech

  • 2020+: Fast charging, solid-state innovation

Chapter 3

Basic Cell Structure

Lithium cell structure with labeled components

Every battery pack is built from cells, and understanding their internal structure is key to understanding performance, safety, and lifespan.

Core components include:

  • Cathode (positive electrode) – Typically NCM, NCA, or LiFePO₄ materials.

  • Anode (negative electrode) – Usually graphite or lithium titanate (LTO).

  • Electrolyte – A liquid medium allowing lithium ions to move between electrodes.

  • Separator – A microporous film that prevents short circuits but lets ions pass through.

  • Shell/Casing – Determines the shape and some thermal behavior of the cell.

Chapter 4

Types of Lithium Batteries

If you’re looking for common lithium battery types for e-bikes, you’ll likely encounter NCM, NCA, and LiFePO₄. Each type balances trade-offs between cost, energy output, charging speed, and safety.

Cathode Material Voltage Energy Density Charge/Discharge Performance Cycle Life Thermal Stability Applications
Lithium Cobalt Oxide (LiCoO2) Nominal 3.6V (Range 3.0–4.2V) 150–240 Wh/kg 0.7–1C, Max 2.5C, >1C shortens lifespan 500–1000 (at standard depth of discharge) 150°C (302°F): risk of thermal runaway Phones, tablets, laptops, cameras, drones
Ternary Material (LiNiCoMnO2) Nominal 3.7V (Range 3.0–4.2V) 150–220 Wh/kg 0.7–1C, Max 2.5–5C, 10C: 3.0Ah cell ~15s 1000–2000 (at standard depth of discharge) 210°C (410°F): stable E-bikes, power tools, EVs, medical, industrial
Lithium Manganese Oxide (LiMn2O4) Nominal 3.7V (Range 3.0–4.2V) 100–150 Wh/kg 0.5–1C, Max 2.5C, 10C: 3.0Ah cell ~15s 300–700 (at standard depth of discharge) 250°C (482°F): stable EVs, power tools, low-cost equipment, seasonal storage
Lithium Iron Phosphate (LiFePO4) Nominal 3.2V (Range 2.5–3.65V) 90–120 Wh/kg 1C typical, up to 30C (5s burst), fast charge/discharge 2000+ (at standard depth of discharge) 270°C (518°F): excellent stability Energy storage systems, EVs, medical, industrial
Lithium Nickel Cobalt Aluminum Oxide (LiNiCoAlO2) Nominal 3.6V (Range 3.0–4.2V) 200–260 Wh/kg 1C typical, Max 5C, charge cut-off voltage 4.2V 500 (at standard depth of discharge) 150°C (302°F): stable High-energy EVs, drones, aerospace
Lithium Titanate (Li4Ti5O12) Nominal 2.4V (Range 1.8–2.85V) 50–80 Wh/kg 1C typical, Max 5C, charge cut-off voltage 2.85V 3000–7000 Stable under 300°C (572°F) UPS, power backup, solar storage, base station batteries
Chapter 5

Cell Forms & Packaging Styles

Another point often misunderstood is the battery structure vs battery pack. A battery cell is a single energy unit, while a pack is a structured combination of cells plus BMS, wiring, and casing. Choosing the right structure depends on your form factor and power needs.

 

  • Cylindrical cells (e.g., 18650, 21700) – Highly standardized and mechanically robust.

  • Prismatic cells – Boxy format, easier for space-efficient pack design.

  • Pouch cells – Lightweight and compact, often used in consumer electronics.

Each format has unique trade-offs between energy density, durability, and manufacturability.

Chapter 6

Key Electrical Parameters

Learning how to read lithium battery specifications like voltage, capacity, and C-rate is essential for comparing suppliers. For example, energy (Wh) is calculated as voltage × capacity, while discharge rate (C rating) helps determine load capability.

 

  • Voltage (V) – Nominal voltage depends on chemistry (3.2V for LFP, 3.7V for NCM/NCA).

  • Capacity (mAh or Ah) – Indicates how much charge a battery can store.

  • Energy (Wh) – Calculated as Voltage × Capacity. Defines usable output.

  • Discharge Rate (C Rating) – The speed at which energy is released. 1C means full discharge in 1 hour.

  • Cycle Life – Number of full charge/discharge cycles before capacity drops below 80%.

Chapter 7

Common Terms You Should Know

Battery performance is tightly linked to the materials used in each part of the cell.

Term Definition
SOC State of Charge – Current battery energy percentage
DOD Depth of Discharge – How much energy is removed per cycle
BMS Battery Management System – Protects and monitors the battery
Cycle Life Number of full charge-discharge cycles
Self-discharge Natural energy loss over time when idle
Chapter 8

Key Battery Materials

Battery performance is tightly linked to the materials used in each part of the cell.

Component Material Function
Cathode NCM / NCA / LFP Stores lithium ions; affects energy & safety
Anode Graphite / LTO Releases lithium ions during discharge
Electrolyte Organic solvent + lithium salt Medium for ion transfer
Separator Microporous polyethylene or polypropylene Prevents short circuit, allows ion flow
Chapter 9

Misconceptions Buyers Should Avoid

Higher capacity always means better battery

Not always. You must balance size, discharge rate, and weight constraints.

All lithium batteries are the same

Different chemistries serve very different purposes.

BMS is optional

Without BMS, lithium batteries can overheat, swell, or even catch fire.

Chapter 10

Summary

By understanding what lithium batteries are made of, how they function, and how different chemistries compare, you’re now better prepared to read specs, compare suppliers, and make informed buying decisions. This chapter lays the groundwork for exploring advanced topics like battery pack design, thermal management, BMS architecture, and international certification in future sections.

Get Free Quote

Need a custom lithium battery pack? Just send us your specs—we’ll help you choose the right voltage, case, and configuration for your application.

Custom Battery Packs Made Easy

At JUNDA, we make customization easy. Follow these 3 simple steps to start today:

🔧 Step 1: Tell Us What You Need

Send your battery requirements — voltage, capacity, casing type, or upload drawings/photos.

💡 Step 2: Get Solution & Quote

We’ll evaluate your specs and recommend the best configuration. A detailed quote will be sent within 24 hours.

🚚 Step 3: Confirm & Produce

After approval and deposit, we start production. Shipping and tracking will be arranged for fast, secure delivery.