Start With the Core: Understanding Lithium Battery Fundamentals

Before diving into performance metrics, compliance, or pack design, it’s essential to master the core concepts of lithium batteries—from chemistry to cell structure.

Whether you’re sourcing batteries for e-bikes, solar systems, or medical devices, understanding the basics helps you avoid common selection errors, communicate with engineers, and make informed decisions.

This page walks you through the core knowledge every professional buyer, engineer, or project manager should know, including battery types, cell structure, material composition, key terms, and typical misunderstandings. No deep BMS theory or testing protocols here—just the essential groundwork.

Frequently Asked Questions – Lithium Battery Basics

What exactly is a lithium battery?

A lithium battery is a rechargeable energy storage device that uses lithium ions to move between the anode and cathode during charge and discharge cycles. It’s known for high energy density, low self-discharge, and long cycle life.

The three main types are cylindrical cells, prismatic cells, and pouch cells. Each type differs in structure, energy density, and suitability for specific applications like e-bikes, power tools, or storage systems.

Core materials include a positive electrode (cathode), negative electrode (anode), separator, electrolyte, and current collectors. These parts work together to enable the flow of lithium ions during operation.

Lithium ions move from the anode to the cathode during discharge and reverse during charging. This electrochemical process allows the battery to store and release energy efficiently.

What's the difference between Li-ion and LiFePO₄ batteries?

Li-ion batteries have higher energy density but lower thermal stability. LiFePO₄ offers longer cycle life and greater safety, making it ideal for applications requiring high reliability.

Cylindrical cells offer excellent mechanical stability, efficient heat dissipation, and mature production processes. They’re commonly used in power tools, e-bikes, and energy storage packs.

Yes—when properly designed with quality materials and BMS protection. Certifications like UN38.3, CE, and UL also help ensure compliance and safety for transport and use.

Absolutely. Battery packs can be tailored with different cell formats, capacities, and configurations depending on your voltage, current, and space requirements.

Table of Contents

Chapter 1

What Is a Lithium Battery?

A lithium battery is a device that stores electrical energy using lithium metal or lithium compounds. Understanding what a lithium battery cell is made of helps buyers assess whether a specific chemistry matches their application’s needs.

 

Broadly speaking, lithium batteries come in two categories:

  • Primary lithium batteries – Non-rechargeable, used in low-power devices.

  • Secondary lithium batteries – Rechargeable, including Li-ion and LiFePO₄ types. The difference between Li-ion and LiFePO4 lies in energy density, safety, and cycle life, making them suitable for different markets like EVs or solar storage.

Chapter 2

History and Development of Lithium Batteries

ithium battery technology began in the 1970s. Sony introduced the first commercial lithium-ion battery in 1991. Today, lithium batteries are widely used in electric vehicles, energy storage, and consumer electronics.

Key Milestones:

  • 1970s: First lithium metal batteries

  • 1991: Sony launches Li-ion

  • 2005–2020: Rise of EV and portable tech

  • 2020+: Fast charging, solid-state innovation

Chapter 3

Basic Cell Structure

Lithium cell structure with labeled components

Every battery pack is built from cells, and understanding their internal structure is key to understanding performance, safety, and lifespan.

Core components include:

  • Cathode (positive electrode) – Typically NCM, NCA, or LiFePO₄ materials.

  • Anode (negative electrode) – Usually graphite or lithium titanate (LTO).

  • Electrolyte – A liquid medium allowing lithium ions to move between electrodes.

  • Separator – A microporous film that prevents short circuits but lets ions pass through.

  • Shell/Casing – Determines the shape and some thermal behavior of the cell.

Chapter 4

Types of Lithium Batteries

If you’re looking for common lithium battery types for e-bikes, you’ll likely encounter NCM, NCA, and LiFePO₄. Each type balances trade-offs between cost, energy output, charging speed, and safety.

Cathode Material Voltage Energy Density Charge/Discharge Performance Cycle Life Thermal Stability Applications
Lithium Cobalt Oxide (LiCoO2) Nominal 3.6V (Range 3.0–4.2V) 150–240 Wh/kg 0.7–1C, Max 2.5C, >1C shortens lifespan 500–1000 (at standard depth of discharge) 150°C (302°F): risk of thermal runaway Phones, tablets, laptops, cameras, drones
Ternary Material (LiNiCoMnO2) Nominal 3.7V (Range 3.0–4.2V) 150–220 Wh/kg 0.7–1C, Max 2.5–5C, 10C: 3.0Ah cell ~15s 1000–2000 (at standard depth of discharge) 210°C (410°F): stable E-bikes, power tools, EVs, medical, industrial
Lithium Manganese Oxide (LiMn2O4) Nominal 3.7V (Range 3.0–4.2V) 100–150 Wh/kg 0.5–1C, Max 2.5C, 10C: 3.0Ah cell ~15s 300–700 (at standard depth of discharge) 250°C (482°F): stable EVs, power tools, low-cost equipment, seasonal storage
Lithium Iron Phosphate (LiFePO4) Nominal 3.2V (Range 2.5–3.65V) 90–120 Wh/kg 1C typical, up to 30C (5s burst), fast charge/discharge 2000+ (at standard depth of discharge) 270°C (518°F): excellent stability Energy storage systems, EVs, medical, industrial
Lithium Nickel Cobalt Aluminum Oxide (LiNiCoAlO2) Nominal 3.6V (Range 3.0–4.2V) 200–260 Wh/kg 1C typical, Max 5C, charge cut-off voltage 4.2V 500 (at standard depth of discharge) 150°C (302°F): stable High-energy EVs, drones, aerospace
Lithium Titanate (Li4Ti5O12) Nominal 2.4V (Range 1.8–2.85V) 50–80 Wh/kg 1C typical, Max 5C, charge cut-off voltage 2.85V 3000–7000 Stable under 300°C (572°F) UPS, power backup, solar storage, base station batteries
Chapter 5

Cell Forms & Packaging Styles

Another point often misunderstood is the battery structure vs battery pack. A battery cell is a single energy unit, while a pack is a structured combination of cells plus BMS, wiring, and casing. Choosing the right structure depends on your form factor and power needs.

 

  • Cylindrical cells (e.g., 18650, 21700) – Highly standardized and mechanically robust.

  • Prismatic cells – Boxy format, easier for space-efficient pack design.

  • Pouch cells – Lightweight and compact, often used in consumer electronics.

Each format has unique trade-offs between energy density, durability, and manufacturability.

Chapter 6

Key Electrical Parameters

Learning how to read lithium battery specifications like voltage, capacity, and C-rate is essential for comparing suppliers. For example, energy (Wh) is calculated as voltage × capacity, while discharge rate (C rating) helps determine load capability.

 

  • Voltage (V) – Nominal voltage depends on chemistry (3.2V for LFP, 3.7V for NCM/NCA).

  • Capacity (mAh or Ah) – Indicates how much charge a battery can store.

  • Energy (Wh) – Calculated as Voltage × Capacity. Defines usable output.

  • Discharge Rate (C Rating) – The speed at which energy is released. 1C means full discharge in 1 hour.

  • Cycle Life – Number of full charge/discharge cycles before capacity drops below 80%.

Chapter 7

Common Terms You Should Know

Battery performance is tightly linked to the materials used in each part of the cell.

Term Definition
SOC State of Charge – Current battery energy percentage
DOD Depth of Discharge – How much energy is removed per cycle
BMS Battery Management System – Protects and monitors the battery
Cycle Life Number of full charge-discharge cycles
Self-discharge Natural energy loss over time when idle
Chapter 8

Key Battery Materials

Battery performance is tightly linked to the materials used in each part of the cell.

Component Material Function
Cathode NCM / NCA / LFP Stores lithium ions; affects energy & safety
Anode Graphite / LTO Releases lithium ions during discharge
Electrolyte Organic solvent + lithium salt Medium for ion transfer
Separator Microporous polyethylene or polypropylene Prevents short circuit, allows ion flow
Chapter 9

Misconceptions Buyers Should Avoid

Higher capacity always means better battery

Not always. You must balance size, discharge rate, and weight constraints.

All lithium batteries are the same

Different chemistries serve very different purposes.

BMS is optional

Without BMS, lithium batteries can overheat, swell, or even catch fire.

Chapter 10

Summary

By understanding what lithium batteries are made of, how they function, and how different chemistries compare, you’re now better prepared to read specs, compare suppliers, and make informed buying decisions. This chapter lays the groundwork for exploring advanced topics like battery pack design, thermal management, BMS architecture, and international certification in future sections.

Chapter 14

What Makes Battery Certifications So Important?

In the lithium battery industry, quality control (QC) isn’t just a process—it’s a buyer’s safeguard. Poor battery quality can lead to overheating, swelling, shortened lifespan, or even serious safety hazards. For B2B buyers—especially those in Europe, North America, and industrial sectors—QC is tied to brand reputation, compliance, and customer trust.

At Junda, we treat every battery pack as a mission-critical component. That’s why we implement a multi-stage QC system—from cell inspection to final pre-shipment tests—ensuring that every battery delivered meets international safety, performance, and traceability standards.

Key benefits of strict QC include:

  • Reduced risk of product recall or failure in the field

  • Improved consistency across batches and production lines

  • Increased trust from partners, resellers, and certification bodies

  • Compliance with regulatory standards like UN38.3, IEC 62133, and ISO 9001

Battery Certifications

Certification Purpose Main Market Applies To
UN38.3 Ensures safe transport of lithium batteries by air/sea Global All lithium batteries
IEC 62133 Covers safety performance and structure of rechargeable cells Global (esp. EU, Asia) Rechargeable lithium batteries
CE Complies with EU health, safety, and environmental laws European Union Electronic devices incl. battery packs
UL (e.g. UL2271) Certifies safety for the U.S. market United States E-mobility, energy storage, tools
RoHS Limits hazardous substances in electronics EU, UK Consumer and industrial electronics
MSDS / SDS Chemical composition and safe handling info Global All chemical battery products

How Certification Requirements Vary by Market and Battery Type?

Different countries and applications demand different sets of certifications.

Whether you’re exporting eBike batteries to Germany or energy storage packs to the U.S., it’s essential to match your battery certification set with the regulatory expectations of the destination market and the battery’s use case.

Region Battery Application Recommended Certifications
EU eBike, Energy Storage, Tools CE, UN38.3, RoHS, IEC 62133, MSDS
United States eBike, UPS, Power Tools UL2271 / UL2580, UN38.3, MSDS
Middle East Energy Storage, Solar Systems UN38.3, IEC 62133, MSDS
Australia ESS, Electric Vehicles, Telecom UN38.3, CE, RoHS, MSDS
Global Transport All lithium batteries UN38.3, MSDS

What Happens If Your Batteries Are Not Certified?

Uncertified batteries pose serious risks—not just to safety, but to your entire business.

Many buyers new to lithium battery sourcing underestimate the consequences of skipping certifications. But in regulated markets like the EU, USA, and Middle East, delivering a non-certified battery pack can lead to shipment detention, legal fines, denied customs clearance, or worse—fires and user injury.

⚠️ Real-World Consequences:
  • 🚫 Rejected Shipments: Customs may block or destroy uncertified batteries (especially without UN38.3 air shipment docs).

  • 🚫 Legal Liability: Injuries or product failures may trigger lawsuits or warranty claims.

  • 🚫 No Air Freight: Without UN38.3, MSDS, and packaging declarations, batteries cannot be shipped by air (IATA DGR rules).

  • 🚫 Importer Blacklisting: Repeat non-compliance can place your company on customs watchlists.

  • 🚫 Brand Damage: Even if your batteries perform well, lack of visible certifications undermines trust in tenders and B2B deals.

How to Obtain Battery Certifications: Step-by-Step Process

Certifying your battery pack is not just paperwork—it’s a proven process involving real testing, documentation, and technical compliance.

Here’s a simplified roadmap to help you navigate certification with confidence, whether you’re targeting CE, UL, or UN38.3:

1. Identify Market Requirements

Decide where the battery will be sold or shipped (EU, US, etc.), and determine which certifications are legally required (e.g., CE, UL, UN38.3).

2. Choose a Testing Laboratory

Select an accredited third-party lab like SGS, TÜV Rheinland, CTI, or Intertek that has experience with lithium battery compliance testing.

3. Submit Technical Documentation

Prepare required documents: circuit diagram, BMS specs, MSDS, cell datasheets, mechanical design drawings, label mockups, and packaging info.

4. Send Battery Samples

Ship representative battery samples to the lab (typically 3–10 pcs), along with packaging material if applicable (for drop/fire tests).

5. Undergo Testing & Evaluation

The lab will test for electrical safety, thermal behavior, transportation safety, labeling compliance, and EMC (if required).

6. Receive Certification Report

Once tests pass, you will receive the official report and/or certificate. CE requires a DoC; UL grants a UL file number; UN38.3 issues a test summary.

Estimated Time & Cost

Certification Lead Time Cost Estimate (USD) Notes
CE (with IEC 62133) 3–4 weeks $2,000–$4,000 EU-focused; includes lab + DoC support
UL2271 / UL2580 6–12 weeks $8,000–$20,000 US safety standard; longer process
UN38.3 7–14 days $800–$2,000 Required for air freight, any country

What Each Certification Means (CE, UL, UN38.3, etc.)?

Each lithium battery certification serves a different purpose—understanding their roles helps you stay compliant and market-ready.

Below is a detailed breakdown of the most important battery certifications, what they prove, and where they apply:

🇪🇺 CE Certification (with EN/IEC 62133)

Purpose:
Confirms the battery meets essential health, safety, and environmental protection standards in the European Economic Area (EEA).

What It Covers:

  • Electrical safety

  • Thermal stability

  • Overcharge, short-circuit, vibration tests

  • Battery management system (BMS) protection validation

Applied Test Standard: EN/IEC 62133-2 for Li-ion batteries.

Required for:
Consumer electronics, eBikes, energy storage systems in the EU market.

🇺🇸 UL Certification (UL2271 / UL2580 / UL2054)

Purpose:
Ensures battery safety and fire protection in the United States, commonly requested in large B2B and industrial contracts.

What It Covers:

  • Fire hazard testing

  • Battery abuse simulations

  • Dielectric resistance

  • Insulation and leakage evaluation

Typical UL Standards:

  • UL2271 for light electric vehicle batteries (e.g., eBikes, scooters)

  • UL2580 for EV/high voltage applications

  • UL2054 for household battery packs

Required for:
North American EV markets, retail chains, and brand certifications.

✈️ UN38.3 Certification

Purpose:
Mandatory for shipping lithium batteries via air (IATA regulations).

What It Covers:

  • Altitude simulation

  • Thermal tests

  • Vibration and shock

  • Overcharge and forced discharge

  • External short-circuit

Required for:
All air shipments globally. Customs will reject shipments without it.

🧪 MSDS (Material Safety Data Sheet)

Purpose:
Describes the chemical composition and handling safety for battery components.

What It Includes:

  • Hazard identification

  • Storage conditions

  • First aid measures

  • Toxicology and reactivity info

Required for:
Hazmat declarations in shipping, safety documentation for large buyers.

🌱 RoHS (Restriction of Hazardous Substances)

Purpose:
Proves that the battery does not contain restricted heavy metals or banned substances.

Limits substances like:

  • Lead (Pb)

  • Mercury (Hg)

  • Cadmium (Cd)

  • Hexavalent Chromium (Cr6+)

Required for:
Selling in Europe, and increasingly adopted in global retail markets.

How to Display Certifications on Products & Documents

Displaying certification labels correctly helps you avoid customs issues, build buyer trust, and pass inspections. Here’s how to apply them on your lithium battery products and associated documents:

  1. Labeling on the Battery Pack

What to Include on the Physical Label:

  • Certification marks (e.g., CE, UL logo)

  • Battery specifications (voltage, capacity, watt-hours)

  • Manufacturer info (name, contact, country of origin)

  • Model number & serial number

  • Warning signs (like “Do not short-circuit” or “Do not disassemble”)

  • Recycling & RoHS symbols

 

Label Placement:

  • For plastic shell packs: laser marking or durable sticker on the top/side

  • For shrink-wrapped soft packs: waterproof label affixed securely

Tip: Labels must be durable, legible, and resistant to wear and solvent exposure per CE/UL requirements.

2. Documentation Requirements

A. Declaration of Conformity (DoC):
This document states that your battery product complies with applicable directives (e.g., CE, RoHS).

Must Include:

  • Manufacturer’s name and address

  • Product description

  • Applicable standards (EN62133, RoHS, etc.)

  • Name and signature of authorized person

  • Issue date

B. UL Test Report & CB Certificate Copies:
Required during customs checks, B2B onboarding, or product audits.

C. UN38.3 Report:
Always attach a full test report + transport certificate when shipping by air.

3. When to Use Certification in Product Listings or Catalogs

Good Practice:

  • Show CE/UL/MSDS/UN38.3 icons with hover tooltips

  • Add clickable “Download Certificate” links in product pages

  • Include a PDF bundle in your sales kit or Alibaba listing

Avoid:

  • Using fake or expired certificates

  • Showing CE mark without EN standard

  • Placing RoHS logo without documentation

Chapter 14

How to Choose the Right Lithium Battery for Your Application

Choosing the right lithium battery is critical for performance, safety, and longevity. Here’s a 6-step method to help you make an informed decision:

1. Define Your Application Scenario

Start with the end use.
The first step is understanding what your battery will power. Each application has its own demands:

  • eBikes / Scooters: Require lightweight, high-current packs

  • Energy Storage Systems: Need long cycle life, stability

  • UPS / Backup Power: Prioritize high reliability

  • Power Tools / Robots: Demand high discharge rates

  • Medical / Telecom / Drone: Require certified, compact packs

 
2. Determine Voltage & Capacity Requirements
  • Match your system’s specs.
    Ask these questions:

    • What voltage does your motor or device require? (12V / 24V / 48V / 72V…)

    • How long should it run per charge? (Ah or Wh determines energy)

    • What is the peak and continuous power draw?

    Higher capacity = longer runtime, but also more weight and cost.

3. Choose Cell Chemistry Based on Use
4. Consider Size and Shape Constraints

Does the battery fit your device?
Common shapes:

  • Triangle Pack: For eBike frame integration

  • Rear Rack / Down Tube: For cargo or city eBikes

  • Wall-Mount / Rack-Mount: For ESS or telecom

  • Compact / Cylindrical / Pouch Cells: For drones, robots, tools

Custom casing and connectors may be needed for tight spaces.

5. Ensure BMS Functionality Matches

Smart battery = safe battery.
The BMS (Battery Management System) controls:

  • Overcharge / over-discharge protection

  • Current limits (C-rating)

  • Thermal shutdown

  • Data monitoring: SOC, SOH, cycle count

  • Protocols: CANBus, RS485, Bluetooth

Choose based on your system’s communication and safety needs.

6. Confirm Certifications & Shipping Readiness

Don’t get blocked at customs.
Key certifications:

  • UN38.3 – Mandatory for air/sea transport

  • CE – Required for EU

  • UL – Required for US

  • MSDS / IEC62133 / RoHS – Safety & environmental

Suppliers should provide test reports, DoC, and labeled packaging.

Chapter 14

Summary

Lithium batteries power everything from eBikes to energy storage systems, but choosing and using them wisely requires more than just knowing the voltage. This guide has walked you through the essentials—from battery cell types, chemistry, and internal structures, to smart BMS systems, testing methods, certifications, lifespan strategies, and safe handling. Whether you’re a buyer, engineer, or brand owner, understanding these fundamentals helps you select safer, more efficient, and fully compliant battery solutions tailored to your application. At the core, it’s not just about batteries—it’s about making smarter, longer-lasting energy decisions.

Get Free Quote

Need a custom lithium battery pack? Just send us your specs—we’ll help you choose the right voltage, case, and configuration for your application.

Custom Battery Packs Made Easy

At JUNDA, we make customization easy. Follow these 3 simple steps to start today:

🔧 Step 1: Tell Us What You Need

Send your battery requirements — voltage, capacity, casing type, or upload drawings/photos.

💡 Step 2: Get Solution & Quote

We’ll evaluate your specs and recommend the best configuration. A detailed quote will be sent within 24 hours.

🚚 Step 3: Confirm & Produce

After approval and deposit, we start production. Shipping and tracking will be arranged for fast, secure delivery.